Publications

Authors:

Bisag, Giorgiana Denisa; Ruggieri, Silvia; Fochi, Mariafrancesca; Bernardi, Luca

Title:

Sulfoxonium ylides: simple compounds with chameleonic reactivity

Year:

2020

Type of item:

Articolo in Rivista

Tipologia ANVUR:

Articolo su rivista

Language:

Inglese

Referee:

No

Name of journal:

ORGANIC & BIOMOLECULAR CHEMISTRY

ISSN of journal:

1477-0520

N° Volume:

18

Number or Folder:

43

Page numbers:

8793-8809

Keyword:

Sulfoxonium ylides

Short description of contents:

Sulfur ylides first disclosed in 1930 started to gain more attention in the 1960s, thanks mainly to the studies by Corey and Chaykovsky on their use for the preparation of strained rings. More recently, the chemistry of these compounds has experienced important growth, in part due to the similarity of their reactivities with diazo compounds. This short review provides an overview on the great assortment of reactions of sulfoxonium ylides, outlining a comparison between the chemistry of these ylides and their congeners: sulfonium ylides and diazo compounds. Insertion reactions, cyclisation reactions and ring-opening reactions are highlighted, giving particular attention to catalytic asymmetric methodologies.

Product ID:

134451

Handle IRIS:

11562/1097630

Last Modified:

June 29, 2023

Bibliographic citation:

Bisag, Giorgiana Denisa; Ruggieri, Silvia; Fochi, Mariafrancesca; Bernardi, Luca, Sulfoxonium ylides: simple compounds with chameleonic reactivity «ORGANIC & BIOMOLECULAR CHEMISTRY» , vol. 18 , n. 43 , 2020 , pp. 8793-8809

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